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• W2171908830 startingPage "85" @default.
• W2171908830 abstract "The first example of a phosphodiester bond cleavage promoted by a highly negatively charged polyoxometalate cluster has been discovered: the hydrolysis of the phosphodiester bond in a DNA model substrate bis(p-nitrophenyl)phosphate (BNPP) is promoted by the heptamolybdate anion [Mo7O24]6− with rates which represent an acceleration of nearly four orders of magnitude compared to the uncatalyzed cleavage." @default.
• W2171908830 created "2016-06-24" @default.
• W2171908830 creator A5027608012 @default.
• W2171908830 creator A5072949993 @default.
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• W2171908830 date "2008-01-01" @default.
• W2171908830 modified "2023-10-03" @default.
• W2171908830 title "Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo₇O₂₄]⁶⁻polyoxometalate cluster as an unlikely catalyst for the hydrolysis of a DNA model substrate" @default.
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• W2171908830 doi "https://doi.org/10.1039/b714860g" @default.
• W2171908830 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18399409" @default.
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