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• W2172033723 startingPage "7439" @default.
• W2172033723 abstract "Blinking statistics in surface-enhanced Raman scattering (SERS) of thiacyanine or thiacarbocyanine adsorbed on single Ag nanoaggregates were analyzed by a power law. A power law reproduces the probability distributions of both the bright and dark SERS occurrences against their duration times. As the localized surface plasmon resonance (LSPR) wavelength of a single Ag nanoaggregate approached the excitation wavelength or the excitation laser intensity increases, the power-law exponents were close to −1.5, a value derived from a one-dimensional random walk model. When the LSPR wavelength left the excitation wavelength or the excitation laser intensity decreases, the power-law exponents deviated from −1.5. The decrease in the power-law exponents in the bright SERS, which indicates a decrease in the probabilities of the long-lived bright SERS, and the increase in the power-law exponents in the dark SERS coincide with the increasing shallowness and narrowing of a optical trapping potential well due to a surface-plasmon-enhanced electromagnetic field around a junction of the Ag nanoaggregates excited at a wavelength apart from the LSPR wavelength or under the low laser intensity, i.e., the low original electromagnetic field, respectively." @default.
• W2172033723 created "2016-06-24" @default.
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• W2172033723 date "2011-01-01" @default.
• W2172033723 modified "2023-09-27" @default.
• W2172033723 title "Power-law analysis of surface-plasmon-enhanced electromagnetic field dependence of blinking SERS of thiacyanine or thiacarbocyanine adsorbed on single silver nanoaggregates" @default.
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• W2172033723 doi "https://doi.org/10.1039/c0cp02802a" @default.
• W2172033723 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21412542" @default.
• W2172033723 hasPublicationYear "2011" @default.
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