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• W2172076180 abstract "We have investigated $3d$ electronic states of doped transition metals in II-VI diluted magnetic semiconductors ${mathrm{Zn}}_{1ensuremath{-}x}{M}_{x}mathrm{Se}(M=mathrm{Mn},mathrm{F}mathrm{e},mathrm{C}mathrm{o})$ and ${mathrm{Zn}}_{1ensuremath{-}x}{mathrm{Mn}}_{x}Y(Y=mathrm{Se},mathrm{Te}),$ using the transition-metal ${L}_{2,3}$-edge x-ray absorption spectroscopy (XAS) measurements. In order to explain the XAS spectra, we employed a tetragonal cluster model calculation, which includes not only the full ionic multiplet structure but also configuration interaction (CI). The results show that CI is essential to describe the experimental spectra adequately, indicating the strong hybridization between the transition metal $3d$ and the ligand p orbitals. In the study of ${mathrm{Zn}}_{1ensuremath{-}x}{mathrm{Mn}}_{x}Y(Y=mathrm{Se},mathrm{Te}),$ we also found considerable spectral change in the Mn ${L}_{2,3}$-edge XAS spectra for different ligands, confirming the importance of the hybridization effects in these materials." @default.
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• W2172076180 date "2001-03-29" @default.
• W2172076180 modified "2023-09-27" @default.
• W2172076180 title "X-ray absorption spectroscopy study of diluted magnetic semiconductors:<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Zn</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mi>−</mml:mi><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi>M</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mi mathvariant=normal>Se</mml:mi><mml:mi /><mml:…" @default.
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• W2172076180 doi "https://doi.org/10.1103/physrevb.63.155203" @default.
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