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- W2172133318 abstract "Abstract Coarse-grained mertieite-II [Pd 8 (Sb,As) 3 ] crystals (up to 2.5 mm across) with inclusions of sperrylite and intergrown with keithconnite [Pd 3 (Te,Bi)], cooperite-braggite, a Pt-Pd-Hg alloy, a (Pd,Pt) 9 Te phase and Au-Ag alloy occur in alluvial sediments in the Darya river, Aldan Shield, Russia. The primary PGM assemblage underwent alteration with formation of a very fine-grained mixture of Pd-bearing oxides and hydrated oxides. The Pd oxide/hydrated oxide aggregates (up to 100 μm wide and ~1 mm long) occur along crystallographic planes, on grain boundaries and fractures, occasionally intergrown with goethite. The Pd-O-bearing compounds formed after (1) mertieite-II (Sb content reaches 23 wt.%), (2) keithconnite (variably enriched in Te, up to 7 wt.% and Bi, up to 6 wt.%) and (3) potarite (with high Hg content, up to 35 wt.%). The variably oxidized and hydrated PGM assemblage can be attributed to supergene alteration and small-scale element redistribution under cool climatic conditions with a limited degree of leaching." @default.
- W2172133318 created "2016-06-24" @default.
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- W2172133318 date "2005-12-01" @default.
- W2172133318 modified "2023-09-27" @default.
- W2172133318 title "Pd-bearing oxides and hydrated oxides in mertieite-II crystals from alluvial sediments of the Darya river, Aldan Shield, Russia" @default.
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- W2172133318 doi "https://doi.org/10.1180/0026461056960303" @default.
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