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• W2172176851 abstract "The mixtures of 2 M 1,4-butanediamine (BDA) and 4 M 2-(diethylamino)-ethanol (DEEA) have been found to be promising biphasic solvents. This work identifies the composition of the lower phase using a DX-120 Ion Chromatograph (IC) and a <i>Metrohm<i/> 809 Titrando auto titrator. The cyclic capacities, cyclic loadings and reaction products of the biphasic solvent are compared with those of the aqueous solution with the same amine concentration as the lower phase of the biphasic solvent at the rich loading ((2B4D)<sub>L<sub/>) using a fast screening facility and a JNM ECA-600 Nuclear Magnetic Resonance spectrometer (NMR). Their absorption rates at different loadings are also investigated using a Wetted Wall Column (WWC). The results show that the cyclic capacity and cyclic loading of (2B4D)<sub>L<sub/> are almost the same as those of 2B4D. The absorption rate of (2B4D)<sub>L<sub/> is higher than 2B4D at all the 3 tested loadings, except for the fresh solutions at CO<sub>2<sub/> pressure lower than 10 kPa. NMR results show that the reaction products of (2B4D)<sub>L<sub/> had more BDA bicarbamate, less BDA and less BDA carbamate than 2B4D. The CO<sub>2<sub/> reaction products of (2B4D)<sub>L<sub/> had twice as much carbonate/bicarbonate as with 2B4D and less BDA carbamate." @default.
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• W2172176851 date "2013-12-04" @default.
• W2172176851 modified "2023-09-25" @default.
• W2172176851 title "CO₂Absorption by Biphasic Solvents: Comparison with Lower Phase Alone" @default.
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• W2172176851 doi "https://doi.org/10.2516/ogst/2013155" @default.
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