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• W2172176885 endingPage "10356" @default.
• W2172176885 startingPage "10348" @default.
• W2172176885 abstract "Abstract We present full details of the unique reactivities of the newly developed dianion‐type bulky zincate, dilithium tetra‐ tert ‐butylzincate ( t Bu 4 ZnLi 2 ). With this reagent, halogen–zinc exchange reaction of variously functionalized haloaromatics and anionic polymerization of N ‐isopropylacrylamide (NIPAm)/styrene with excellent chemoselectivity were realized. Halogen–zinc exchange reaction followed by electrophilic trapping with propargyl bromide provided a convenient route to functionalized phenylallenes, particularly those with electrophilic functional groups (such as cyano, amide and halogens). Spectral and computational studies of the structure in the gas and liquid phases indicated extraordinary stabilization of this dianion‐type zincate by its bulky ligands." @default.
• W2172176885 created "2016-06-24" @default.
• W2172176885 creator A5000147737 @default.
• W2172176885 creator A5031119452 @default.
• W2172176885 creator A5050408192 @default.
• W2172176885 creator A5069421930 @default.
• W2172176885 creator A5072582041 @default.
• W2172176885 creator A5086823406 @default.
• W2172176885 date "2008-11-10" @default.
• W2172176885 modified "2023-10-18" @default.
• W2172176885 title "Development of Highly Chemoselective Bulky Zincate Complex,<i>t</i>Bu₄ZnLi₂: Design, Structure, and Practical Applications in Small-/Macromolecular Synthesis" @default.
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• W2172176885 doi "https://doi.org/10.1002/chem.200800536" @default.
• W2172176885 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18816554" @default.
• W2172176885 hasPublicationYear "2008" @default.

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