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• W2172187524 endingPage "14093" @default.
• W2172187524 startingPage "14090" @default.
• W2172187524 abstract "A molybdenum-dithiolene-oxo complex was prepared as a model of some active sites of Mo/W-dependent enzymes. The ligand, a quinoxaline-pyran-fused dithiolene, mimics molybdopterin present in these active sites. For the first time, this type of complex was shown to be active as a catalyst for the photoreduction of protons with excellent turnover numbers (500) and good stability in aqueous/organic media and for the electroreduction of protons in acetonitrile with remarkable rate constants (1030 s(-1) at -1.3 V versus Ag/AgCl). DFT calculations provided insight into the catalytic cycle of the reaction, suggesting that the oxo ligand plays a key role in proton exchange. These results provide a basis to optimize this new class of H2 -evolving catalysts." @default.
• W2172187524 created "2016-06-24" @default.
• W2172187524 creator A5022444398 @default.
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• W2172187524 date "2015-09-25" @default.
• W2172187524 modified "2023-10-18" @default.
• W2172187524 title "A Bioinspired Molybdenum Complex as a Catalyst for the Photo- and Electroreduction of Protons" @default.
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• W2172187524 doi "https://doi.org/10.1002/anie.201505607" @default.
• W2172187524 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26404460" @default.
• W2172187524 hasPublicationYear "2015" @default.
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