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- W2172265612 abstract "The present work deals with the synthesis, characterization and cadmium adsorption studies on SiO2, Fe(OH)3 and their mixed oxides. Mixed oxides of iron and silicon of composition [0.5 M SiO2:0.5 M Fe(OH)3] were prepared by physical mixing (M1) and sequential precipitation methods (M2). The selectivity of adsorbents towards Cd2+ ion was found to be in the order M2 > M1 = Fe(OH)3 > silica. Dissolution of silica, mixed oxides M1 and M2 was also investigated in the pH range 3–10. The greater dissolution of mixed oxide M2, along with the higher selectivity towards Cd2+ ions showed the formation of the ternary complexes on the surface of M2. The complex formation was also confirmed by IR studies and by the increase in Cd2+ sorption with the addition of the silicates anions in the medium. The thermodynamic parameters showed the Cd2+ sorption to be endothermic and spontaneous in nature." @default.
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- W2172265612 date "2010-02-15" @default.
- W2172265612 modified "2023-09-25" @default.
- W2172265612 title "Selective sorption of cadmium by mixed oxides of iron and silicon" @default.
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- W2172265612 doi "https://doi.org/10.1016/j.cej.2009.10.036" @default.
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