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- W2172567413 abstract "Reduction of the enantiopure β-amino esters 10 provides the γ-amnio alcohol 11, which is condensed with 2,4-pentadione to afford 12. Stepwise cyclization of 12 produced the cyclic enamine 13, which is hydrogenated to deliver all cis-2,3,6-trisubstituted piperidine 14. Using this reaction sequence and subsequent Baeyer–Villiger oxidation as the key step (−)-deoxocassine and (+)-azimic acid are synthesized." @default.
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- W2172567413 date "2003-05-01" @default.
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- W2172567413 title "Stereospecific route to enantiopure all cis-2,3,6-trisubstituted piperidines. Facile synthesis of (−)-deoxocassine and (+)-azimic acid" @default.
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- W2172567413 doi "https://doi.org/10.1016/s0040-4039(03)00820-7" @default.
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