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- W2172886225 abstract "α-Fluoroacrylonitriles 2 were synthesized in moderate to good yields by Horner–Wittig (HW) reaction of aldehydes and ketones with (diphenylphosphinoyl)fluoroacetonitrile (1), prepared in situ from commercially available fluoroacetonitrile and diphenylphosphinyl chloride. New synthetic applications of 2 are presented with the one-pot conversion into 2-fluoroallylamines 6 and C-(1-fluorovinyl)nitrones 8 through a diisobutylaluminum hydride (DIBALH)-reduction transimination protocol. The scope and limitations of this procedure are discussed." @default.
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- W2172886225 date "2004-01-01" @default.
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- W2172886225 title "α-Fluoroacrylonitriles: Horner–Wittig synthesis and conversion into 2-fluoroallylamines and C-(1-fluorovinyl)nitrones" @default.
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- W2172886225 doi "https://doi.org/10.1016/j.jfluchem.2003.11.001" @default.
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