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• W2172968285 abstract "The first total synthesis of two E type I phytoprostanes from furan, azelaic acid monomethyl ester and rac-1,2-epoxybutane is described. The key features of our synthetic strategy encompass an enzymatic kinetic resolution of a hydroxycyclopentenone, a Co-salen hydrolytic kinetic resolution of a terminal epoxide and a tandem conjugate addition/diastereoselective protonation sequence to construct the protected phytoprostanes. Mild cleavage of the silyl protective groups followed by enzymatic ester hydrolysis afforded the free E-type phytoprostanes." @default.
• W2172968285 created "2016-06-24" @default.
• W2172968285 creator A5037918415 @default.
• W2172968285 creator A5059546138 @default.
• W2172968285 date "2003-09-01" @default.
• W2172968285 modified "2023-09-30" @default.
• W2172968285 title "First total synthesis of the E type I phytoprostanes" @default.
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• W2172968285 doi "https://doi.org/10.1016/j.tetlet.2003.08.042" @default.
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