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- W2173146226 abstract "An enantioselective synthesis of (R)-salbutamol has been carried out using the chiral, C2 symmetric acyl anion equivalent, (1R,3R)-1,3-dithiane 1,3-dioxide, which undergoes addition to an aromatic aldehyde with very high stereocontrol at 0 °C. Pummerer reaction and work-up with lithium ethanethiolate generated the α-hydroxy thiolester in high yield and further transformations led to the target compound with high enantiomeric excess." @default.
- W2173146226 created "2016-06-24" @default.
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- W2173146226 date "2002-11-01" @default.
- W2173146226 modified "2023-09-23" @default.
- W2173146226 title "Application of the Chiral Acyl Anion Equivalent, <i>trans</i>-1,3-Dithiane 1,3-Dioxide, to an Asymmetric Synthesis of (<i>R</i>)-Salbutamol" @default.
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- W2173146226 doi "https://doi.org/10.1021/jo026410i" @default.
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