FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2173331310> ?p ?o ?g. }

• W2173331310 endingPage "539" @default.
• W2173331310 startingPage "532" @default.
• W2173331310 abstract "Ethylamine (EA) often serves as a surrogate species to represent aliphatic amines that occur in biofuels. This contribution reports, for the first time, the thermochemical and kinetic parameters for bimolecular reactions of EA with three prominent radicals that form in the initial stages of biomass decomposition; namely, H, CH3 and NH2. Abstraction of a methylene H atom from the EA molecule largely dominates H loss from the two other sites (i.e., methyl and amine hydrogens) for the three considered radicals. We demonstrate that, differences in bond dissociation enthalpies of methylene C–H bonds among EA, ethanol and propane reflect their corresponding HOMO/LUMO energy gaps. At low and intermediate temperatures, the rate of H abstraction from the methylene site in EA exceeds the corresponding values for propane and ethanol. As the temperature rises, matching entropic factors induce comparable rate constants for the three molecules." @default.
• W2173331310 created "2016-06-24" @default.
• W2173331310 creator A5009961264 @default.
• W2173331310 creator A5081335004 @default.
• W2173331310 creator A5082950378 @default.
• W2173331310 creator A5089916818 @default.
• W2173331310 date "2016-01-01" @default.
• W2173331310 modified "2023-09-30" @default.
• W2173331310 title "Decomposition of ethylamine through bimolecular reactions" @default.
• W2173331310 cites W1965106118 @default.
• W2173331310 cites W1967950200 @default.
• W2173331310 cites W1977012521 @default.
• W2173331310 cites W1994973833 @default.
• W2173331310 cites W1996441017 @default.
• W2173331310 cites W2002020855 @default.
• W2173331310 cites W2003590677 @default.
• W2173331310 cites W2017202176 @default.
• W2173331310 cites W2019984430 @default.
• W2173331310 cites W2024145920 @default.
• W2173331310 cites W2026980390 @default.
• W2173331310 cites W2033619041 @default.
• W2173331310 cites W2035196826 @default.
• W2173331310 cites W2056129977 @default.
• W2173331310 cites W2068220576 @default.
• W2173331310 cites W2068613445 @default.
• W2173331310 cites W2071955309 @default.
• W2173331310 cites W2080022417 @default.
• W2173331310 cites W2087067846 @default.
• W2173331310 cites W2090663866 @default.
• W2173331310 cites W2109492863 @default.
• W2173331310 cites W2111596229 @default.
• W2173331310 cites W2135582827 @default.
• W2173331310 cites W2137710436 @default.
• W2173331310 cites W2140871833 @default.
• W2173331310 cites W2142856157 @default.
• W2173331310 cites W2150345533 @default.
• W2173331310 cites W2171445884 @default.
• W2173331310 cites W2332086337 @default.
• W2173331310 doi "https://doi.org/10.1016/j.combustflame.2015.10.032" @default.
• W2173331310 hasPublicationYear "2016" @default.
• W2173331310 type Work @default.
• W2173331310 sameAs 2173331310 @default.
• W2173331310 citedByCount "22" @default.
• W2173331310 countsByYear W21733313102017 @default.
• W2173331310 countsByYear W21733313102018 @default.
• W2173331310 countsByYear W21733313102019 @default.
• W2173331310 countsByYear W21733313102020 @default.
• W2173331310 countsByYear W21733313102021 @default.
• W2173331310 countsByYear W21733313102022 @default.
• W2173331310 countsByYear W21733313102023 @default.
• W2173331310 crossrefType "journal-article" @default.
• W2173331310 hasAuthorship W2173331310A5009961264 @default.
• W2173331310 hasAuthorship W2173331310A5081335004 @default.
• W2173331310 hasAuthorship W2173331310A5082950378 @default.
• W2173331310 hasAuthorship W2173331310A5089916818 @default.
• W2173331310 hasBestOaLocation W21733313102 @default.
• W2173331310 hasConcept C102931765 @default.
• W2173331310 hasConcept C121332964 @default.
• W2173331310 hasConcept C124681953 @default.
• W2173331310 hasConcept C139066938 @default.
• W2173331310 hasConcept C147597530 @default.
• W2173331310 hasConcept C147789679 @default.
• W2173331310 hasConcept C148898269 @default.
• W2173331310 hasConcept C155647269 @default.
• W2173331310 hasConcept C178790620 @default.
• W2173331310 hasConcept C185592680 @default.
• W2173331310 hasConcept C2776345496 @default.
• W2173331310 hasConcept C2777454769 @default.
• W2173331310 hasConcept C2778678469 @default.
• W2173331310 hasConcept C32909587 @default.
• W2173331310 hasConcept C62396407 @default.
• W2173331310 hasConcept C62520636 @default.
• W2173331310 hasConcept C75473681 @default.
• W2173331310 hasConcept C93391505 @default.
• W2173331310 hasConceptScore W2173331310C102931765 @default.
• W2173331310 hasConceptScore W2173331310C121332964 @default.
• W2173331310 hasConceptScore W2173331310C124681953 @default.
• W2173331310 hasConceptScore W2173331310C139066938 @default.
• W2173331310 hasConceptScore W2173331310C147597530 @default.
• W2173331310 hasConceptScore W2173331310C147789679 @default.
• W2173331310 hasConceptScore W2173331310C148898269 @default.
• W2173331310 hasConceptScore W2173331310C155647269 @default.
• W2173331310 hasConceptScore W2173331310C178790620 @default.
• W2173331310 hasConceptScore W2173331310C185592680 @default.
• W2173331310 hasConceptScore W2173331310C2776345496 @default.
• W2173331310 hasConceptScore W2173331310C2777454769 @default.
• W2173331310 hasConceptScore W2173331310C2778678469 @default.
• W2173331310 hasConceptScore W2173331310C32909587 @default.
• W2173331310 hasConceptScore W2173331310C62396407 @default.
• W2173331310 hasConceptScore W2173331310C62520636 @default.
• W2173331310 hasConceptScore W2173331310C75473681 @default.
• W2173331310 hasConceptScore W2173331310C93391505 @default.
• W2173331310 hasFunder F4320312169 @default.
• W2173331310 hasFunder F4320334704 @default.
• W2173331310 hasLocation W21733313101 @default.
• W2173331310 hasLocation W21733313102 @default.
• W2173331310 hasLocation W21733313103 @default.
• W2173331310 hasOpenAccess W2173331310 @default.

• next