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- W2173895593 abstract "In the title compound, {(C20H20N4)2[Mo8O26]}n, the asymmetric unit contains half of an [Mo8O26]4− anion and one 3,3′-[(biphenyl-4,4′-diyl)dimethylene]diimidazol-1-ium dication. In the anion, four distorted [MoO6] octahedra are connected via edge-sharing, forming an [Mo4O13]2− building block, composed of Mo—O(t), Mo—O(μ2), Mo—O(μ3) and Mo—O(μ4) units, with Mo—O distances ranging from 1.6858 (15) to 2.4785 (13) Å. The γ-type [Mo8O26]4− anion is completed by crystallographic inversion symmetry and is linked into an infinite chain along [100] by corner-sharing. The anionic chains and the cations are joined by N—H⋯O hydrogen bonds, generating layers extending parallel to (001)." @default.
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- W2173895593 date "2010-03-24" @default.
- W2173895593 modified "2023-09-27" @default.
- W2173895593 title "Poly[bis{3,3′-[(biphenyl-4,4′-diyl)dimethylene]diimidazol-1-ium} γ-octamolybdate(VI)]" @default.
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- W2173895593 doi "https://doi.org/10.1107/s1600536810010111" @default.
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