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- W2174385336 abstract "Abstract The analytic expressions for the dynamic coefficient of thermal conductivity λ(ω) and for the dynamic module of thermoelasticity Z(ω) of the electrolyte solutions are obtained by the use of kinetic equations for the one-particle f a x → a t and two-particle f ab x → a x → b t distribution functions. We restrict our attention to the spherical symmetric case and simple semi-phenomenological model in the framework of the osmotic theory of electrolyte solutions at the definite values of interaction potential Φ ab r → and the equilibrium pair distribution function g ab r → . We investigate the frequency dispersion and perform numerical calculations of λ(ω) and Z(ω) for NaCl aqueous solution as function of temperature T at a fixed ion concentration C. Theoretical results for temperature dependence of λ are in quantitative agreement with experimental data. It is shown that a field of frequency dispersion of λ(ω) and Z(ω) is wide if the diffusion mechanism, i.e. the structural relaxation, is taken into account." @default.
- W2174385336 created "2016-06-24" @default.
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- W2174385336 date "2015-12-01" @default.
- W2174385336 modified "2023-09-27" @default.
- W2174385336 title "Dependence of thermoelastic properties of aqueous electrolyte solutions on the frequency and temperature" @default.
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- W2174385336 doi "https://doi.org/10.1016/j.molliq.2015.09.025" @default.
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