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- W2174421830 endingPage "199" @default.
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- W2174421830 abstract "Abstract A series of novel biaryl ureas containing different structural patterns have been prepared in good yields in the presence of palladium nanoparticles (PdNPs) with narrow particle size distribution. In particular, α, β‐, and γ‐hydroxypropylated cyclodextrins were used as reductants/stabilizers under different Pd‐to‐cyclodextrin ratios to tune the particle size and exploit the surface/cavity effects in the Suzuki–Miyaura reaction. Catalyst recovery in this process was pursued as well. Owing to its excellent performance, ceria was explored as a support for these PdNPs. The heterogeneous catalyst was characterized and investigated in the reaction of N ‐(4‐iodo‐aryl), N ′‐alkyl urea and phenylboronic acid. Our preliminary results revealed a high activity of the catalyst at 0.5 mol % Pd 0 during three consecutive cycles. It is suggested that the specific interface between Pd 0 and the high‐surface‐area ceria has a role in the catalytic performance." @default.
- W2174421830 created "2016-06-24" @default.
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- W2174421830 creator A5062283496 @default.
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- W2174421830 date "2015-11-23" @default.
- W2174421830 modified "2023-09-27" @default.
- W2174421830 title "Selectivity Studies Towards the Synthesis of Novel Biaryl Ureas by (Hetero)Nanocatalysis: Size Control and Support Effects" @default.
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- W2174421830 doi "https://doi.org/10.1002/cctc.201500889" @default.
- W2174421830 hasPublicationYear "2015" @default.
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