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- W2174445132 abstract "Abstract A synthetic route to 1-benzyl-tetrahydro-1-benzazepine is reported, which also permits access to analogous structures with alkyl and aryl substituents at position-2 of the aliphatic ring. Palladium catalysis is utilized in two of the three steps, constructing the seven-membered rings effectively from 2-bromoiodobenzene. Competitive β-hydride elimination was observed in the attempted carbonnitrogen bond formation with a sterically bulky substrate (when R=tert-butyl)." @default.
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- W2174445132 date "2003-08-05" @default.
- W2174445132 modified "2023-09-27" @default.
- W2174445132 title "Synthesis of 2-Substituted 1-Benzyl-2,3,4,5-tetrahydro-1-benzazepines by Palladium Catalysis. Observation of a Competitive β-Hydride Elimination Pathway." @default.
- W2174445132 cites W2949898553 @default.
- W2174445132 doi "https://doi.org/10.1002/chin.200331186" @default.
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