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• W2175439407 abstract "The reactions of [Cp*IrCl2]2 (Cp* = pentamethylcyclopentadienyl) with [M6O19]8– (M = Nb, Ta) anions lead to the formation of new hybrid organometallic–polyoxometalate (organometallic–POM) complexes, namely, single-capped Na8[H2{Cp*IrNb6O18}2(O)]·47H2O (Na8-IrNb12) and Na6[{Cp*Ir}Ta6O19]·27H2O (Na6-IrTa6) as well as double-capped trans-[{Cp*Ir}2M6O19]4– complexes. Their solution behavior was studied by NMR spectroscopy and ESI-MS techniques. Cyclic voltammetry (CV) experiments demonstrated efficient electrocatalytic water oxidation in the presence of trans-[{Cp*Ir}2Nb6O19]4–." @default.
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• W2175439407 date "2015-11-18" @default.
• W2175439407 modified "2023-10-16" @default.
• W2175439407 title "Coordination of {C ₅ Me ₅ Ir} ²⁺ to [M ₆ O ₁₉ ] ^8– (M = Nb, Ta) – Analogies and Differences between Rh and Ir, Nb and Ta" @default.
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• W2175439407 doi "https://doi.org/10.1002/ejic.201501051" @default.
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