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- W2176202318 abstract "We report a cascade synthetic route to directly obtain diethyl terephthalate, a replacement for terephthalic acid, from biomass-derived muconic acid, ethanol, and ethylene. The process involves two steps: First, a substituted cyclohexene system is built through esterification and Diels-Alder reaction; then, a dehydrogenation reaction provides diethyl terephthalate. The key esterification reaction leads to improved solubility and modulates the electronic properties of muconic acid, thus promoting the Diels-Alder reaction with ethylene. With silicotungstic acid as the catalyst, nearly 100% conversion of muconic acid was achieved, and the cycloadducts were formed with more than 99.0% selectivity. The palladium-catalyzed dehydrogenation reaction preferentially occurs under neutral or mildly basic conditions. The total yield of diethyl terephthalate reached 80.6% based on the amount of muconic acid used in the two-step synthetic process." @default.
- W2176202318 created "2016-06-24" @default.
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- W2176202318 date "2015-11-23" @default.
- W2176202318 modified "2023-10-17" @default.
- W2176202318 title "Production of Diethyl Terephthalate from Biomass‐Derived Muconic Acid" @default.
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- W2176202318 doi "https://doi.org/10.1002/anie.201509149" @default.
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