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- W2176367008 abstract "The asymmetric unit of the title compound, [FeCo2(C5H5)2(C3H3S3)S(C18H15P)(CO)]CF3SO3, consists of a triangular irondicobalt cluster cation and a trifluoromethanesulfonate anion. In the cation, the FeCo2 triangle is symmetrically capped on one face by an S atom and on the other by a C atom linked to a methyl trithiocarbonate residue that bridges the Fe—C bond. Each Co atom carries a cyclopentadienyl ligand while the Fe atom coordinates to one carbonyl and one triphenylphosphine ligand. In the crystal structure, the cation is linked to the anion by a number of weak non-classical C—H⋯O and C—H⋯F hydrogen bonds and weak S⋯O (3.317 Å) and S⋯F (3.198 Å) interactions. The structure is further stabilized by additional intermolecular C—H⋯O, C—H⋯F and O⋯O (2.942 Å) contacts, together with an unusual S⋯π(Cp) interaction (S⋯centroid distance = 3.385 Å), generating an extended network." @default.
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- W2176367008 date "2008-04-10" @default.
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- W2176367008 title "(Carbonyl-1κ<i>C</i>)bis[2,3(η<sup>5</sup>)-cyclopentadienyl][μ<sub>3</sub>-(<i>S</i>-methyl trithiocarbonato)methylidyne-1:2:3κ<sup>4</sup><i>C</i>,<i>S</i>′′:<i>C</i>:<i>C</i>](triphenylphosphine-1κ<i>P</i>)(μ<sub>3</sub>-sulfido-1:2:3κ<sup>3</sup><i>S</i>)dicobalt(II)iron(II) trifluoromethanesulfonate" @default.
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- W2176367008 doi "https://doi.org/10.1107/s1600536808008970" @default.
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