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- W2176760116 abstract "Gallium metal is effective in mediating the allylation of various carbonyl compounds and imines under solvent-free conditions, with the application of sonic energy, affording the corresponding homoallylic alcohols and amines. The imines themselves were also prepared under solventless conditions in high yield, thereby establishing a two-step solvent-free synthesis of homoallylic amines. In comparison, indium metal produced a mixture of the desired homoallylic secondary amine and the bis-allylated species via an iminium ion intermediate." @default.
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- W2176760116 date "2004-01-01" @default.
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- W2176760116 title "Gallium metal mediated allylation of carbonyl compounds and imines under solvent-free conditions" @default.
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- W2176760116 doi "https://doi.org/10.1016/j.tetlet.2003.10.188" @default.
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