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- W2176974458 abstract "Abstract Addition of ethylene to the carbanions formed by the metallation of the lithium salts of di- and trimethylphenols by the strongly basic system, n -BuLi-LiK(OCH 2 CH 2 NMe 2 ) 2 provides a useful synthetic route to a range of alkylphenols. The ease of alkylation of the methyl groups decreases in the order ortho > meta > para while the inclusion of Mg(OCH 2 CH 2 OEt) 2 in the catalyst restricts alkylation to the methyl groups ortho to the hydroxy group. Dialkylation occurs only at the ortho -methyl groups and only if the adjacent meta -position is unsubstituted. The potential of these products for the synthesis of sterically hindered ligands is outlined." @default.
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- W2176974458 date "2006-03-01" @default.
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- W2176974458 title "Selective catalytic carbanionic ethylation of methylphenols: influence of catalyst and substitution pattern" @default.
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- W2176974458 doi "https://doi.org/10.1016/j.tetlet.2006.01.133" @default.
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