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- W2176985295 abstract "Enantioenriched allenes serve as chiral transfer reagents, making them attractive synthetic targets. Herein, the synthesis of enantioenriched allenes utilizing a Pd(0)-catalyzed cross-coupling reaction of propargylic carbonates and phosphates with alkenyl trifluoroborates is reported. Di-, tri-, and tetrasubstituted allenes were synthesized in moderate to high optical yields. Several racemic allenes possessing various functional groups were also synthesized." @default.
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- W2176985295 date "2006-01-24" @default.
- W2176985295 modified "2023-09-30" @default.
- W2176985295 title "Palladium(0)-Catalyzed Synthesis of Chiral Ene-allenes Using Alkenyl Trifluoroborates" @default.
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- W2176985295 doi "https://doi.org/10.1021/jo052201x" @default.
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