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- W2177080145 abstract "Silica and alumina were used as structural promoters to increase the catalytic activity of a co-precipitated Fe–Cu–K catalyst for the CO2 and CO hydrogenation during Fischer–Tropsch (FT) synthesis. The doubly-promoted Fe–Cu–K–Si–Al catalyst achieved higher CO and CO2 conversions than the Fe–Cu–K catalyst and singly-promoted Fe–Cu–K–Al and Fe–Cu–K–Si catalysts. The CO and CO2 conversions of the syngas with 54% H2/10% CO/29% CO2/7% N2 over the doubly-promoted catalyst were 88.3% and 25.2%, respectively, compared to 81.8% and 18.5% for the Fe–Cu–K catalyst. In this case, the C5+ selectivity of the doubly-promoted catalyst was 71.9%, which was slightly lower than 75.5% for the Fe–Cu–K catalyst. The CO2 was converted to hydrocarbons using the doubly-promoted catalyst when the CO2/(CO + CO2) ratio was higher than 0.35 for H2-balanced syngas at H2/(2CO + 3CO2) = 1.0, and 0.5 for H2-deficient syngas at H2/(2CO + 3CO2) = 0.5. The increase of hydrogen content in the syngas increased the methane selectivity at the expense of decrease in the liquid hydrocarbon selectivity." @default.
- W2177080145 created "2016-06-24" @default.
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- W2177080145 date "2015-12-01" @default.
- W2177080145 modified "2023-10-04" @default.
- W2177080145 title "Effect of silica and alumina promoters on co-precipitated Fe–Cu–K based catalysts for the enhancement of CO2 utilization during Fischer–Tropsch synthesis" @default.
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- W2177080145 doi "https://doi.org/10.1016/j.jcou.2015.10.002" @default.
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