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- W2178311384 abstract "Aromatic amine phosphonato esters 4a–d were obtained in excellent yields from the 1:1:1 addition reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate in the presence of NH-aromatic amines such as 2-aminobenzophenone, 2-aminoacetophenon, methyl-2-aminobenzoate, and 2-aminobenzonitrile. In the recent works, the assignments of the configuration of 4a–d corresponding to the three-bond carbon-phosphorus coupling, 3Jpc, was determined on the basis of coupling constants by the Karplus equation as 2R*,3R*or 2S*,3S* while they were 2R*,3S* or 2S*,3R* in our previous works in the presence of same solvent. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:240–245, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20541" @default.
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- W2178311384 date "2009-01-01" @default.
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- W2178311384 title "Synthesis of aromatic amine phosphonato ester derivatives from the stereoselective reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate in the presence of derivatives of aromatic amines" @default.
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- W2178311384 doi "https://doi.org/10.1002/hc.20541" @default.
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