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- W2178660443 abstract "Abstract A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed by us. The present work demonstrates the synthetic potential of the method for the synthesis of polypropionate antibiotics including ansamycins and macrolides." @default.
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- W2178660443 date "1993-09-01" @default.
- W2178660443 modified "2023-10-02" @default.
- W2178660443 title "Synthetic studies on polypropionate antibiotics based on the stereospecific methylation of γ δ-epoxy acrylates by trimethylaluminum. A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins" @default.
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- W2178660443 doi "https://doi.org/10.1016/s0040-4039(00)73733-6" @default.
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