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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2178667033> ?p ?o ?g. }

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• W2178667033 abstract "The thermal reactions of the closed-shell, naked gold-carbene complex [Au(CH2)](+) with methane have been explored by using FTICR mass spectrometry complemented by quantum chemical (QC) calculations at the CCSD(T)//BMK level of theory. Mechanistic aspects for this unprecedentedly efficient carbene insertion in the C-H bond of methane have been addressed and the origin of the counterintuitive high reactivity of [Au(CH2)](+) towards this most inert hydrocarbon is discussed." @default.
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• W2178667033 date "2015-11-18" @default.
• W2178667033 modified "2023-10-06" @default.
• W2178667033 title "Efficient Room-Temperature, Au⁺ -Mediated Coupling of a Carbene Ligand with Methane To Generate C₂ H_<i>x</i> (<i>x=</i> 4, 6)" @default.
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• W2178667033 doi "https://doi.org/10.1002/anie.201509320" @default.
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