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- W2178698183 abstract "Abstract A stable glyoxylate can be successfully applied to both syn - and anti -selective aldol reactions by using two different kinds of ordinary Lewis acids. Thus, treatment of bowl-shaped tris(2,6-diphenylbenzyl)silyl glyoxylate 1 with enol silyl ether under the influence of BF 3 ·OEt 2 gave syn -aldol product, while the use of TiCl 4 afforded anti -aldol product with >97% selectivity." @default.
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- W2178698183 date "2003-01-01" @default.
- W2178698183 modified "2023-09-27" @default.
- W2178698183 title "Synthetic utility of bowl-shaped tris(2,6-diphenyl-benzyl)silyl glyoxylate as a stable glyoxylate: application to highly diastereoselective aldol reactions" @default.
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- W2178698183 doi "https://doi.org/10.1016/s0040-4039(02)02557-1" @default.
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