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- W2178730319 endingPage "4063" @default.
- W2178730319 startingPage "4056" @default.
- W2178730319 abstract "Organometallic Fe complexes with exceptionally high activities in homogeneous epoxidation catalysis are reported. The compounds display Fe(II) and Fe(III) oxidation states and bear a tetracarbene ligand. The more active catalyst exhibits activities up to 183 000 turnovers per hour at room temperature and turnover numbers of up to 4300 at -30 °C. For the Fe(III) complex, a decreased Fenton-type reactivity is observed compared with Fe(II) catalysts reported previously as indicated by a substantially lower H2 O2 decomposition and higher (initial) turnover frequencies. The dependence of the catalyst performance on the catalyst loading, substrate, water addition, and the oxidant is investigated. Under all applied conditions, the advantageous nature of the use of the Fe(III) complex is evident." @default.
- W2178730319 created "2016-06-24" @default.
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- W2178730319 creator A5020618455 @default.
- W2178730319 creator A5057122501 @default.
- W2178730319 creator A5070593505 @default.
- W2178730319 date "2015-11-17" @default.
- W2178730319 modified "2023-10-09" @default.
- W2178730319 title "Fighting Fenton Chemistry: A Highly Active Iron(III) Tetracarbene Complex in Epoxidation Catalysis" @default.
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- W2178730319 doi "https://doi.org/10.1002/cssc.201500930" @default.
- W2178730319 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26580492" @default.
- W2178730319 hasPublicationYear "2015" @default.
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