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- W2179175537 abstract "Micropatterns of hydrophilic polymer brushes were prepared by micromolding in capillaries (MIMIC). The polymers are covalently bound to the surfaces by a rapid hetero Diels-Alder reaction, constituting the first example of polymers grafted to surfaces in a defined pattern by MIMIC. The polymers [poly(acrylic acid), poly(hydroxyethyl acrylate), and poly(tetraethylene glycol acrylate) ranging in molecular weight from 1500 to 6000 g mol(-1)] were prepared with narrow dispersities via the reversible addition-fragmentation chain transfer (RAFT) process using a highly electron deficient RAFT agent that can react with surface-anchored dienes such as cyclopentadiene. We demonstrate that the anchoring method is facile to perform and highly suitable for preparing patterned surfaces that are passivated against biological impact in well-defined areas." @default.
- W2179175537 created "2016-06-24" @default.
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- W2179175537 date "2015-12-08" @default.
- W2179175537 modified "2023-09-24" @default.
- W2179175537 title "Fast and Simple Preparation of Patterned Surfaces with Hydrophilic Polymer Brushes by Micromolding in Capillaries" @default.
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- W2179175537 doi "https://doi.org/10.1021/acs.langmuir.5b03924" @default.
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