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- W2179366923 abstract "Exfoliation/restacking route was adopted to investigate layer-by-layer self-assembly of α-ZrP/CoTMPyP [5, 10, 15, 20-tetrakis (N-methylpyridinium-4-yl) porphyrinato cobalt (III)] sandwich-structured nanocomposite in our research. The well-dispersed α-ZrP colloidal suspension in tetra-n-butylammonium hydroxide (TBA+OH−) aqueous solution whose zeta potential value is −40.1 mV was obtained. Besides, supported by XRD, IR, UV–vis, SEM, TEM, and TG-DTA, the CoTMPyP molecules were successfully introduced into the lamellar spacing of α-ZrP host material. Cyclic voltammetry measurements of α-ZrP/CoTMPyP hybrid film suggested the self-assembled product showed excellent electrocatalytic activities toward oxygen reduction with the reduction peak potential shifting from −0.692 V (bare glass carbon electrode) to −0.203 V (modified electrode). Moreover, the curves of the reduction peak current and the square root of scan rate presented good linear relationship, implying a diffusion-controlled process." @default.
- W2179366923 created "2016-06-24" @default.
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- W2179366923 date "2016-03-01" @default.
- W2179366923 modified "2023-10-18" @default.
- W2179366923 title "Sandwich-structured nanocomposite constructed by fabrication of exfoliation α-ZrP nanosheets and cobalt porphyrin utilized for electrocatalytic oxygen reduction" @default.
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- W2179366923 doi "https://doi.org/10.1016/j.micromeso.2015.11.015" @default.
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