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• W2179558229 abstract "The supramolecular interaction of 2,4-dichlorophenol (2,4-DCP) and β-cyclodextrin functionalized ionic liquid, a mono-6-deoxy-6-(3-benzylimidazolium)-β-cyclodextrin tosylate (β-CD-BIMOTs) has been investigated. The inclusion complex of β-CD-BIMOTs-2,4-DCP complex was analyzed with conventional spectroscopic techniques and compared with native β-CD-2,4-DCP complex. The mechanism of the inclusion too was studied and discussed based on FTIR, 1H NMR and 2D NOESY analysis. β-CD-BIMOTs has a stronger binding affinity towards 2,4-DCP compared to native β-CD based on the formation constant value calculated. In this work, modified electrodes were fabricated by mixing β-CD-BIMOTs and carbon paste electrode (CPE) for determination of 2,4-DCP. The electrochemical behavior of 2,4-DCP at β-CD-BIMOTs/CPE exhibits higher electrochemical performance than that of native β-CD/CPE and CPE, revealing that CPE modified β-CD-BIMOTs not only displays good electrical properties of the ionic liquid but also exhibits high supramolecular recognition properties of β-CD-BIMOTs through the formation of an inclusion complex between β-CD-BIMOTs and 2,4-DCP molecules. This preliminarily study shows that β-CD-BIMOTs can act as an inexpensive electrochemical sensor that is suitable for the determination of 2,4-DCP." @default.
• W2179558229 created "2016-06-24" @default.
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• W2179558229 date "2015-12-01" @default.
• W2179558229 modified "2023-10-18" @default.
• W2179558229 title "Supramolecular interaction of 2,4-dichlorophenol and β-cyclodextrin functionalized ionic liquid and its preliminary study in sensor application" @default.
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• W2179558229 doi "https://doi.org/10.1016/j.molliq.2015.10.044" @default.
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