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- W2179673921 abstract "The first detailed study of the palladium-catalyzed amination of aryl nonaflates is reported. Use of ligands 2−4 and 6 allows for the catalytic amination of electron-rich and -neutral aryl nonaflates with both primary and secondary amines. With use of Xantphos 5, the catalytic amination of a variety of functionalized aryl nonaflates resulted in excellent yields of anilines; even 2-carboxymethyl aryl nonaflate is effectively coupled with a primary alkylamine. Moderate yields were obtained when coupling halo-aryl nonaflates with a variety of amines, where in most cases the aryl nonaflate reacted in preference to the aryl halide. Overall, aryl nonaflates are an effective alternative to triflates in palladium-catalyzed C−N bond-forming processes due to their increased stability under the reaction conditions." @default.
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- W2179673921 date "2003-11-13" @default.
- W2179673921 modified "2023-10-13" @default.
- W2179673921 title "Palladium-Catalyzed Amination of Aryl Nonaflates" @default.
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- W2179673921 doi "https://doi.org/10.1021/jo034962a" @default.
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