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- W2179891965 abstract "The crystal structures of three hydrogen-bonded co-crystals of 4-alkoxybenzoic acid–4,4′-bipyridyl (2/1), namely, 2C 9 H 10 O 3 ·C 10 H 8 N 2 , (I), 2C 10 H 12 O 3 ·C 10 H 8 N 2 , (II) and 2C 11 H 14 O 3 ·C 10 H 8 N 2 , (III), have been determined at 93 K. Although the structure of (I) has been determined in the space group P 2 1 with Z = 4 [Lai et al. (2008). J. Struct. Chem. 49 , 1137–1140], the present study shows that the space group is P 2 1 / n with Z = 4. In each crystal, the components are linked by O—H...N hydrogen bonds, forming a linear hydrogen-bonded 2:1 unit of the acid and the base. The 2:1 unit of (I) adopts nearly pseudo- C 2 symmetry, viz . twofold rotation around an axis passing through the mid-point of the central C—C bond of 4,4′-bipyridyl, while the units of (II) and (III), except for the terminal alkyl chains, have pseudo-inversion symmetry. The 2:1 units of (I), (II) and (III) are linked via C—H...O hydrogen bonds, forming sheet, double-tape and tape structures, respectively." @default.
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- W2179891965 date "2015-10-07" @default.
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- W2179891965 title "Crystal structures of three co-crystals of 4,4′-bipyridyl with 4-alkoxybenzoic acids: 4-ethoxybenzoic acid–4,4′-bipyridyl (2/1), 4-<i>n</i>-propoxybenzoic acid–4,4′-bipyridyl (2/1) and 4-<i>n</i>-butoxybenzoic acid–4,4′-bipyridyl (2/1)" @default.
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- W2179891965 doi "https://doi.org/10.1107/s2056989015018435" @default.
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