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- W2179969440 abstract "Stereoselectivity of the titanium-mediated aldol process based on (S)-2-benzyloxy-3-pentanone, 1, is dramatically modified by the presence of a Lewis acid. Among the Lewis acids surveyed, TiCl4 has given access to the corresponding 2,4-anti-4,5-syn aldol adducts with the highest diastereomeric ratios. The excellent stereocontrol exerted by the aforementioned ketone has been demonstrated in double asymmetric reactions involving chiral α-methyl-β-OTBDPS aldehydes." @default.
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- W2179969440 date "2004-07-01" @default.
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- W2179969440 title "Stereoselective titanium-mediated syn -aldol reaction from a lactate-derived chiral ethyl ketone" @default.
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- W2179969440 doi "https://doi.org/10.1016/j.tetlet.2004.05.077" @default.
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