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• W2180419360 abstract "The mini article highlights the versatility of Ni-Al hydrotalcite (HT) catalysts using molecular oxygen as oxidant compared to Ni/SiO 2 , Ni and other catalysts reported for oxidation of alcohols to carbonyl compounds. Among the catalysts reported in literature to date, Ni-Al HT is the best catalyst s suited for molecular oxygen initiated oxidation of alcohols to carbonyl compounds. Benzylic alcohols, substitute benzylic, allylic, ?-ketols and substituted cinnamyl alcohols are oxidized to aldehydes and ketones. Ni in association with oxide of aluminium is the active precursor for the title reaction and Ni-Al HT catalysts was characterized by TPR, XRD, IR, and DSC. Ni/SiO 2 also exhibited some activity for oxidation of alcohols to carbonyl compounds with 30% H 2 O 2 as oxidant, whereas, Ni/TiO 2 did not exhibit activity for the title reaction which is due to uneven distribution of Ni on TiO 2 surface. Hence, from these results, it is evident that Ni hydrotalcite catalysts with molecular oxygen is the active catalysts for alcohol oxidation to carbonyl compounds which have valuable applications in fine chemical industry and academia." @default.
• W2180419360 created "2016-06-24" @default.
• W2180419360 creator A5006654638 @default.
• W2180419360 creator A5030032712 @default.
• W2180419360 date "2015-10-20" @default.
• W2180419360 modified "2023-09-24" @default.
• W2180419360 title "A Green Protocol for Selective Oxidation of Alcohols to Carbonyl Compounds Comparative Studies with Various Ni Heterogeneous Catalysts with O2 and H2O2 as Oxidants." @default.
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