FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2180760246> ?p ?o ?g. }

• W2180760246 endingPage "3820" @default.
• W2180760246 startingPage "3810" @default.
• W2180760246 abstract "The iron(III) complex of hexadentate N,N,N'-tris(2-pyridylmethyl)ethylendiamine-N'-acetate (tpena(-) ) is a more effective homogenous catalyst for selective sulfoxidation and epoxidation with insoluble iodosylbenzene, [PhIO]n , compared with soluble methyl-morpholine-N-oxide (NMO). We propose that two molecules of [Fe(tpena)](2+) cooperate to solubilize PhIO, extracting two equivalents to form the halogen-bonded dimeric {[Fe(tpena)OIPh]2}(4+). The closest intradimeric I⋅⋅⋅O distance, 2.56 Å, is nearly 1 Å less than the sum of the van de Waals radii of these atoms. A correlation of the rates of the reaction of {[Fe(tpena)OIPh]2}(4+) with para-substituted thioanisoles indicate that this species is a direct metal-based oxidant rather than a derived ferryl or perferryl complex. A study of gas-phase reactions indicate that an ion at m/z=231.06100 originates from solution-state {[Fe(tpena)OIPh]2}(4+) and is ascribed to [Fe(III) (tpenaO)](2+), derived from an intramolecular O atom insertion into an Fe-tpena donor bond. Proposed ion pairs, {[Fe(tpena)OIPh]Cl}(+) and {[Fe(tpena)OIPh]ClO4}(+), are more stable than native [Fe(tpena)OIPh](2+) ions, suggesting that halogen-bonding, as for the solution and solid states, operates also in the gas phase." @default.
• W2180760246 created "2016-06-24" @default.
• W2180760246 creator A5002305569 @default.
• W2180760246 creator A5002648736 @default.
• W2180760246 creator A5041777006 @default.
• W2180760246 creator A5045582222 @default.
• W2180760246 creator A5049385313 @default.
• W2180760246 creator A5060887111 @default.
• W2180760246 creator A5078793021 @default.
• W2180760246 date "2015-11-24" @default.
• W2180760246 modified "2023-10-12" @default.
• W2180760246 title "Halogen-Bonding-Assisted Iodosylbenzene Activation by a Homogenous Iron Catalyst" @default.
• W2180760246 cites W1582265535 @default.
• W2180760246 cites W1966608829 @default.
• W2180760246 cites W1972846946 @default.
• W2180760246 cites W1975462662 @default.
• W2180760246 cites W1979233077 @default.
• W2180760246 cites W1982274469 @default.
• W2180760246 cites W1987336986 @default.
• W2180760246 cites W1997952970 @default.
• W2180760246 cites W2012090737 @default.
• W2180760246 cites W2013429454 @default.
• W2180760246 cites W2014916013 @default.
• W2180760246 cites W2016651664 @default.
• W2180760246 cites W2022757946 @default.
• W2180760246 cites W2023958219 @default.
• W2180760246 cites W2024170242 @default.
• W2180760246 cites W2029366738 @default.
• W2180760246 cites W2030841140 @default.
• W2180760246 cites W2031434538 @default.
• W2180760246 cites W2032424617 @default.
• W2180760246 cites W2038429535 @default.
• W2180760246 cites W2039018268 @default.
• W2180760246 cites W2042704692 @default.
• W2180760246 cites W2047601015 @default.
• W2180760246 cites W2058223824 @default.
• W2180760246 cites W2062847668 @default.
• W2180760246 cites W2065168135 @default.
• W2180760246 cites W2072635052 @default.
• W2180760246 cites W2076587517 @default.
• W2180760246 cites W2078083100 @default.
• W2180760246 cites W2083650713 @default.
• W2180760246 cites W2090543751 @default.
• W2180760246 cites W2092604020 @default.
• W2180760246 cites W2095543408 @default.
• W2180760246 cites W2098886669 @default.
• W2180760246 cites W2105047194 @default.
• W2180760246 cites W2107195312 @default.
• W2180760246 cites W2109805812 @default.
• W2180760246 cites W2122282600 @default.
• W2180760246 cites W2122290971 @default.
• W2180760246 cites W2133770352 @default.
• W2180760246 cites W2135892715 @default.
• W2180760246 cites W2142120024 @default.
• W2180760246 cites W2143120654 @default.
• W2180760246 cites W2144923541 @default.
• W2180760246 cites W2151456957 @default.
• W2180760246 cites W2156120263 @default.
• W2180760246 cites W2159677696 @default.
• W2180760246 cites W2160575068 @default.
• W2180760246 cites W2161136708 @default.
• W2180760246 cites W2170088615 @default.
• W2180760246 cites W2312736635 @default.
• W2180760246 cites W2320452819 @default.
• W2180760246 cites W2323134732 @default.
• W2180760246 cites W2323207391 @default.
• W2180760246 cites W2327012774 @default.
• W2180760246 cites W2327723489 @default.
• W2180760246 cites W2328106156 @default.
• W2180760246 cites W2332544306 @default.
• W2180760246 cites W2950751110 @default.
• W2180760246 cites W4232253731 @default.
• W2180760246 cites W4232482127 @default.
• W2180760246 cites W4235538670 @default.
• W2180760246 cites W4236571175 @default.
• W2180760246 cites W4238558286 @default.
• W2180760246 cites W4239918484 @default.
• W2180760246 cites W4240722129 @default.
• W2180760246 cites W4240807757 @default.
• W2180760246 cites W4248491373 @default.
• W2180760246 doi "https://doi.org/10.1002/chem.201503112" @default.
• W2180760246 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26598789" @default.
• W2180760246 hasPublicationYear "2015" @default.
• W2180760246 type Work @default.
• W2180760246 sameAs 2180760246 @default.
• W2180760246 citedByCount "38" @default.
• W2180760246 countsByYear W21807602462016 @default.
• W2180760246 countsByYear W21807602462017 @default.
• W2180760246 countsByYear W21807602462018 @default.
• W2180760246 countsByYear W21807602462019 @default.
• W2180760246 countsByYear W21807602462020 @default.
• W2180760246 countsByYear W21807602462021 @default.
• W2180760246 countsByYear W21807602462022 @default.
• W2180760246 countsByYear W21807602462023 @default.
• W2180760246 crossrefType "journal-article" @default.
• W2180760246 hasAuthorship W2180760246A5002305569 @default.
• W2180760246 hasAuthorship W2180760246A5002648736 @default.
• W2180760246 hasAuthorship W2180760246A5041777006 @default.

• next