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• W2181328701 abstract "Hyperconjugation between the CH2Si bond and the charged pyridinium π system in the N-methyl 4-trimethylsilylmethyl pyridinium ion (8), manifests in the crystal structure as lengthening of the CH2Si bond, shortening of the CH2Cipso bond and smaller but systematic effects on the CC bond distances within the pyridinium ring. The structural effects are supported in solution by systematic effects on the 29Si–13C and 13C–13C one-bond coupling constants." @default.
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• W2181328701 date "2002-10-01" @default.
• W2181328701 modified "2023-09-23" @default.
• W2181328701 title "Carbon–silicon hyperconjugation" @default.
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• W2181328701 doi "https://doi.org/10.1016/s0022-328x(02)01595-4" @default.
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