Matches in SemOpenAlex for { <https://semopenalex.org/work/W2183354654> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2183354654 endingPage "721" @default.
- W2183354654 startingPage "715" @default.
- W2183354654 abstract "Di-1,1-chlorophenyl-2,2,2-trichloroethane (DDT) and its derivatives di-1,1-chlorophenyl-2,2dichloroethane (DDD), di-1,1-chlorophenyl-2,2-dichloroethene (DDE), and di-1,1-chlorophenyl-2-chloroethene (DDMU) were dechlorinated in heptane solution over a sulphide Ni-Mo/C catalyst in a batch reactor. The process was carried out at 150-260oC and hydrogen pressure of 3 MPa. For DDT, fast elimination of chlorine was observed from the aliphatic position, yielding mainly DDD at 150oC. At around 200oC, the aromatic chlorine atoms started to be removed. The complete dechlorination of the DDT derivatives was observed at 260oC, yielding predominantly 1,1-diphenylethane (DPE) and 1,2-diphenylethane (BB). The conversion of DDT to BB was found to proceed via DDD. BB was presumably formed via carbenoid rearrangement of geminal dichlorides. Small amounts of diphenylmethane (DPM) were also found in the final product. Based on the GCMS and GC-FID analyses of reaction products, the pathways of DDT derivative degradations during hydrodechlorination (HDCl) were proposed." @default.
- W2183354654 created "2016-06-24" @default.
- W2183354654 creator A5008504887 @default.
- W2183354654 creator A5052847204 @default.
- W2183354654 date "2010-01-01" @default.
- W2183354654 modified "2023-09-24" @default.
- W2183354654 title "Conversion pathways of DDT and its derivatives during catalytic hydrodechlorination." @default.
- W2183354654 cites W1972228332 @default.
- W2183354654 cites W1977394666 @default.
- W2183354654 cites W1978301191 @default.
- W2183354654 cites W2005506244 @default.
- W2183354654 cites W2006432241 @default.
- W2183354654 cites W2010914962 @default.
- W2183354654 cites W2017415896 @default.
- W2183354654 cites W2018605102 @default.
- W2183354654 cites W2028186661 @default.
- W2183354654 cites W202868326 @default.
- W2183354654 cites W2035822339 @default.
- W2183354654 cites W2042080178 @default.
- W2183354654 cites W2044064182 @default.
- W2183354654 cites W2048369727 @default.
- W2183354654 cites W2086924914 @default.
- W2183354654 cites W2095290632 @default.
- W2183354654 cites W2130004825 @default.
- W2183354654 cites W2161193457 @default.
- W2183354654 cites W2952164197 @default.
- W2183354654 cites W93906944 @default.
- W2183354654 hasPublicationYear "2010" @default.
- W2183354654 type Work @default.
- W2183354654 sameAs 2183354654 @default.
- W2183354654 citedByCount "0" @default.
- W2183354654 crossrefType "journal-article" @default.
- W2183354654 hasAuthorship W2183354654A5008504887 @default.
- W2183354654 hasAuthorship W2183354654A5052847204 @default.
- W2183354654 hasConcept C155647269 @default.
- W2183354654 hasConcept C161790260 @default.
- W2183354654 hasConcept C178790620 @default.
- W2183354654 hasConcept C179104552 @default.
- W2183354654 hasConcept C185592680 @default.
- W2183354654 hasConcept C2776920668 @default.
- W2183354654 hasConcept C2779758233 @default.
- W2183354654 hasConcept C2781033668 @default.
- W2183354654 hasConcept C505241676 @default.
- W2183354654 hasConcept C521398313 @default.
- W2183354654 hasConceptScore W2183354654C155647269 @default.
- W2183354654 hasConceptScore W2183354654C161790260 @default.
- W2183354654 hasConceptScore W2183354654C178790620 @default.
- W2183354654 hasConceptScore W2183354654C179104552 @default.
- W2183354654 hasConceptScore W2183354654C185592680 @default.
- W2183354654 hasConceptScore W2183354654C2776920668 @default.
- W2183354654 hasConceptScore W2183354654C2779758233 @default.
- W2183354654 hasConceptScore W2183354654C2781033668 @default.
- W2183354654 hasConceptScore W2183354654C505241676 @default.
- W2183354654 hasConceptScore W2183354654C521398313 @default.
- W2183354654 hasIssue "4" @default.
- W2183354654 hasLocation W21833546541 @default.
- W2183354654 hasOpenAccess W2183354654 @default.
- W2183354654 hasPrimaryLocation W21833546541 @default.
- W2183354654 hasRelatedWork W1974932389 @default.
- W2183354654 hasRelatedWork W1980966622 @default.
- W2183354654 hasRelatedWork W1998885829 @default.
- W2183354654 hasRelatedWork W2001919921 @default.
- W2183354654 hasRelatedWork W2006382766 @default.
- W2183354654 hasRelatedWork W2014304524 @default.
- W2183354654 hasRelatedWork W2024890383 @default.
- W2183354654 hasRelatedWork W2027509187 @default.
- W2183354654 hasRelatedWork W2034955345 @default.
- W2183354654 hasRelatedWork W2050398102 @default.
- W2183354654 hasRelatedWork W2052215272 @default.
- W2183354654 hasRelatedWork W2053657094 @default.
- W2183354654 hasRelatedWork W2079816309 @default.
- W2183354654 hasRelatedWork W2105182235 @default.
- W2183354654 hasRelatedWork W2340144500 @default.
- W2183354654 hasRelatedWork W2389319391 @default.
- W2183354654 hasRelatedWork W2417205355 @default.
- W2183354654 hasRelatedWork W2810151188 @default.
- W2183354654 hasRelatedWork W3211423629 @default.
- W2183354654 hasRelatedWork W2186508520 @default.
- W2183354654 hasVolume "19" @default.
- W2183354654 isParatext "false" @default.
- W2183354654 isRetracted "false" @default.
- W2183354654 magId "2183354654" @default.
- W2183354654 workType "article" @default.