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- W2183555641 abstract "In this work we show dipole-assisted photogated switching by covalent grafting of photoactive molecules to conducting polymers. Photochromic spiropyran molecules were covalently attached to polyaniline (PANI) nanowires via N-alkylation reaction to the quinoic part of PANI. Upon irradiation with ultraviolet light spiropyran transformed to a large dipole containing molecule, merocyanine form. We show that this transformation leads to a substantial (ca. 2 orders of magnitude) increase in conductance of the photochromic PANI nanowires, which were evident by an increase in field-effect mobility and calculated band gap narrowing of the system. Finally, this transformation was found to be fully reversible with no significant photofatigue." @default.
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- W2183555641 date "2011-02-03" @default.
- W2183555641 modified "2023-10-06" @default.
- W2183555641 title "Dipole Assisted Photogated Switch in Spiropyran Grafted Polyaniline Nanowires" @default.
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- W2183555641 doi "https://doi.org/10.1021/jp110665j" @default.
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