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- W2183586952 abstract "Ethynylation of various tryptophan-containing peptides and a single model protein was achieved using Waser's reagent, 1-[(triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1 H)-one (TIPS-EBX), under gold(I) catalysis. It was demonstrated by NMR that the ethynylation occurred selectively at the C2-position of the indole ring of tryptophan. Further, MS/MS showed that the tryptophan residues could be modified selectively with ethynyl functionalities even when the tryptophan was present as a part of the protein. Finally, the terminal alkyne was used to label a model peptide with a fluorophore by means of copper-catalyzed click chemistry." @default.
- W2183586952 created "2016-06-24" @default.
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- W2183586952 date "2015-12-22" @default.
- W2183586952 modified "2023-10-18" @default.
- W2183586952 title "Chemo‐ and Regioselective Ethynylation of Tryptophan‐Containing Peptides and Proteins" @default.
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- W2183586952 doi "https://doi.org/10.1002/chem.201504462" @default.
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