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- W2183610877 abstract "The measurements of ultrasonic velocity and density were made for the ternary mixtures o f benzyl chloride and bromobenzene with a-cresol in a non-polar solvent, carbon tetrachloride at various concentration s for varying temperatures (30, 40, 50 °C) at a frequency of 2 MHz. Various ph ysical parameters such as adiabatic compressibility, intermolecular free length and their excesses in mixtures, molar sound velocity, molar compressibi lit y, acoustic impedance and degree of intermolecul ar attraction were evaluated . Weak molecular interactions taking part between th e unlike molecules o f solute in each mixture have been studied through these physical parameters and th eir excess values. The ultrasonic velocity shows a maximum for each mixture at specific temperatu res, exhibiting maxim.um interaction s occurring between solu te molecules at that parti cular concentrat ion givin g rise to complex formation. On further in creasing or decreas in g the concentrati on, molecular association decreases. The excess va lu e data evalu ated for these mixtures also support th e existence of complex formation . The experimental ve lo cities have been compared with theoretically estimated velociti es using Nomoto rel ation and also ideal mixing relation . The deviati on of theoretical valu es of velociti es from experimental valu es also supports the ex istence of complex formation ." @default.
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- W2183610877 date "2002-01-01" @default.
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- W2183610877 title "Ultrasonic investigations of X... HO bond complexes" @default.
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