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- W2183620066 abstract "The electronic structure of a material plays an important role in its functionality for different applications which can be probed using synchrotron-based spectroscopy techniques. Here, various cobalt-based compounds, differing in crystal structure, ligands surrounding the central metal ion and morphology, have been studied by soft X-ray absorption spectroscopy (XAS) at the Co L-edge in order to measure the effect of these parameters on the electronic structure. A careful qualitative analysis of the spectral branching ratio and relative intensities of the L3 and L2 peaks provide useful insight into the electronic properties of compounds such as CoO/Co(OH)2, CoCl2.6H2O/CoF2.4H2O, CoCl2/CoF2, Co3O4 (bulk/nano/micro). For further detailed analysis of the XAS spectra, quantitative analysis has been performed by fitting the spectral profile with simulated spectra for a number of cobalt compounds using crystal field atomic multiplet calculations." @default.
- W2183620066 created "2016-06-24" @default.
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- W2183620066 date "2015-10-16" @default.
- W2183620066 modified "2023-10-16" @default.
- W2183620066 title "Influence of crystal structure, ligand environment and morphology on Co<i>L</i>-edge XAS spectral characteristics in cobalt compounds" @default.
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- W2183620066 doi "https://doi.org/10.1107/s1600577515017178" @default.
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