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- W2183669937 abstract "The absorption and emission spectra of 4f–4f transitions of K2Pr(NO3)5(H2O)2 and K2La(1−x)Prx(NO3)5(H2O)2 (with 0<x≤1) are reported for different temperatures and Pr3+ concentrations. The degeneracy lifting of the rare-earth ion in the crystal leads to an approximate C3 symmetry, sub-group of a quasi-icosahedral symmetry. The influence of the Pr3+ –Pr3+ interactions on the population of the excited levels is demonstrated. Crystal field parameter calculations have been performed with 18 experimental energy levels and the results are compared to previous calculations based on fewer transitions." @default.
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- W2183669937 date "2006-11-01" @default.
- W2183669937 modified "2023-09-30" @default.
- W2183669937 title "Spectroscopic study of Praseodymium(III) bidentate nitrate dihydrate complexes: and" @default.
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- W2183669937 doi "https://doi.org/10.1016/j.jallcom.2005.10.091" @default.
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