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• W2183789964 abstract "The oxidation of the ternary complex, [Cr(III)(Gu)(Asp)(H2O)2]2+ (Gu = guanosine and Asp = DL-aspartic acid) by periodate in aqueous solution to chromium(VI) has been studied spectrophotometrically over the 25–45owith respect to both [IO4–] and [Cr(III)], and increases with pH over the 2.38–3.68 range. The experimental rate law is consistent with the derived mechanism and the reaction follows the rate law:d[Cr(III)]/dt = (k1K5 + k2K6K1/[H+])[IO4–][Cr(III)]T/{1 + K1/[H+] + (K5 + K1K6/[H+])[IO4–]},where K1, K5 and K6 are the deprotonation of [Cr(III)(Gu)(Asp)(H2O)2]2+ and pre-equilibrium formation constants for [Cr(III)(Gu)(Asp)(H2O)(OIO3)]+ and [Cr(III)(Gu)(Asp)(OH)OIO3] precursor complexes, respectively. The reaction may follow a 2-step inner-sphere electron transfer mechanism via coordination of IO4– to chromium(III). Thermodynamic activation parameters have been calculated." @default.
• W2183789964 created "2016-06-24" @default.
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• W2183789964 date "2014-01-01" @default.
• W2183789964 modified "2023-09-27" @default.
• W2183789964 title "MECHANISM OF ELECTRON TRANSFER FOR THE OXIDATION OF TERNARY COMPLEX OF CHROMIUM(III) INVOLVING GUANOSINE AND DL-ASPARTIC ACID WITH PERIODATE" @default.
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• W2183789964 hasPublicationYear "2014" @default.
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