Matches in SemOpenAlex for { <https://semopenalex.org/work/W2184223839> ?p ?o ?g. }
Showing items 1 to 59 of
59
with 100 items per page.
- W2184223839 endingPage "85" @default.
- W2184223839 startingPage "82" @default.
- W2184223839 abstract "Lewisite (L) and mustard gas (HD) are highly toxic vesicant warfare agents that are very sparingly soluble in water and thereby converted quantitatively to the stable and soluble degradation products 2-chlorovinylarsonous acid (CVAA), 2-chloro vinylarsonic acid (CVAOA), 2,2’-dihydroxyethyl sulphide and 2,2’-dichlorodiethyl sulphoxide. A new method based on reversed-phase high performance liquid chromatography (RP-HPLC) has been developed for the simultaneous detection of CVAOA, CVAA, 2,2’-dichlorodiethyl sulphoxide, 2,2’-dihydroxyethyl sulphide. The effects of eluent and pH on the separation efficiency were studied. UV spectra of CVAOA, CVAA, 2,2’-dichlorodiethyl sulphoxide and 2,2’-dihydroxyethyl sulphide were recorded. Good separation was achieved by HPLC using a 250 × 4.6 mm column with 5 μm ODS C18 after optimization of all relevant parameters. The calibration curves ofCVAOA,CVAA, 2,2’-dichlorodiethyl sulphoxide and 2,2’-dihydroxyethyl sulphide showed high linearity over a concentration range of 5–500, 2–500, 5–500, 50–1000 mg L –1 , respectively. The detection limits at a signal-to-noise ratio of 3 were 0.001, 0.2, 2, 20mgL –1 . The method may be beneficial for studying the distribution of lewisite-and/or mustard gas and their degradation products in the environment. Keywords: High performance liquid chromatography, 2-chlorovinylarsonic acid, -chlorovinylarsonous acid, 2,2’-dichlorodiethyl sulphoxide, 2,2’-dihydroxyethyl sulphide." @default.
- W2184223839 created "2016-06-24" @default.
- W2184223839 creator A5018056185 @default.
- W2184223839 creator A5061843207 @default.
- W2184223839 creator A5063972629 @default.
- W2184223839 creator A5079826846 @default.
- W2184223839 creator A5090114853 @default.
- W2184223839 date "2005-01-01" @default.
- W2184223839 modified "2023-09-27" @default.
- W2184223839 title "The determination of degradation products of lewisite and / or mustard gas in water by high performance liquid chromatography" @default.
- W2184223839 hasPublicationYear "2005" @default.
- W2184223839 type Work @default.
- W2184223839 sameAs 2184223839 @default.
- W2184223839 citedByCount "1" @default.
- W2184223839 crossrefType "journal-article" @default.
- W2184223839 hasAuthorship W2184223839A5018056185 @default.
- W2184223839 hasAuthorship W2184223839A5061843207 @default.
- W2184223839 hasAuthorship W2184223839A5063972629 @default.
- W2184223839 hasAuthorship W2184223839A5079826846 @default.
- W2184223839 hasAuthorship W2184223839A5090114853 @default.
- W2184223839 hasConcept C123460561 @default.
- W2184223839 hasConcept C179998833 @default.
- W2184223839 hasConcept C185592680 @default.
- W2184223839 hasConcept C2779679103 @default.
- W2184223839 hasConcept C41008148 @default.
- W2184223839 hasConcept C43617362 @default.
- W2184223839 hasConcept C51724486 @default.
- W2184223839 hasConcept C76155785 @default.
- W2184223839 hasConceptScore W2184223839C123460561 @default.
- W2184223839 hasConceptScore W2184223839C179998833 @default.
- W2184223839 hasConceptScore W2184223839C185592680 @default.
- W2184223839 hasConceptScore W2184223839C2779679103 @default.
- W2184223839 hasConceptScore W2184223839C41008148 @default.
- W2184223839 hasConceptScore W2184223839C43617362 @default.
- W2184223839 hasConceptScore W2184223839C51724486 @default.
- W2184223839 hasConceptScore W2184223839C76155785 @default.
- W2184223839 hasIssue "1" @default.
- W2184223839 hasLocation W21842238391 @default.
- W2184223839 hasOpenAccess W2184223839 @default.
- W2184223839 hasPrimaryLocation W21842238391 @default.
- W2184223839 hasRelatedWork W1991068782 @default.
- W2184223839 hasRelatedWork W2023700440 @default.
- W2184223839 hasRelatedWork W2071793933 @default.
- W2184223839 hasRelatedWork W2072022590 @default.
- W2184223839 hasRelatedWork W2080036987 @default.
- W2184223839 hasRelatedWork W2082241335 @default.
- W2184223839 hasRelatedWork W2085125235 @default.
- W2184223839 hasRelatedWork W2085997598 @default.
- W2184223839 hasRelatedWork W2095596928 @default.
- W2184223839 hasRelatedWork W2124689705 @default.
- W2184223839 hasRelatedWork W92076795 @default.
- W2184223839 hasRelatedWork W142583106 @default.
- W2184223839 hasVolume "58" @default.
- W2184223839 isParatext "false" @default.
- W2184223839 isRetracted "false" @default.
- W2184223839 magId "2184223839" @default.
- W2184223839 workType "article" @default.