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- W2184469401 abstract "A novel aspect of the medium-range structure of silica drawn into fibers is studied. The network of silica glass structure is composed of corner-shared SiO4 tetrahedra, and it can be seen as a structure of interconnected rings (Si–O)n of various size, denoted nMR (n-membered ring). Molecular dynamics simulations show that small-sized silica rings get a preferential orientation during the drawing, either during the high-temperature stage for 3MR, or during the cooling for 4MR and 5MR, and they persist in this state in the fiber at ambient temperature. This leads to a structural anisotropy, more specifically a “transverse isotropy”, because of different longitudinal and transversal physical properties. This anisotropic structural rearrangement during the drawing process induces a non-Newtonian behavior of the modeled glass melt, with strain-rate dependent properties." @default.
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- W2184469401 date "2016-02-01" @default.
- W2184469401 modified "2023-10-17" @default.
- W2184469401 title "Deformation of silica glass studied by molecular dynamics: Structural origin of the anisotropy and non-Newtonian behavior" @default.
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- W2184469401 doi "https://doi.org/10.1016/j.jnoncrysol.2015.11.029" @default.
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