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- W2184495737 abstract "The complexes of Mn(II), Fe(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pd(II) with 4- {(E)-(1-(1H-benzo(d)imidazol-2-yl)ethylidene)amino}-3-methyl-1H-1,2, 4-triazole-5(4H)-thione (Hbzeamt) and with 4-{(E)-(1-(1H-benzo(d)imidazol-2-yl)phenylmethyleneamino)-3-methyl-1H-1, 2, 4-triazole-5(4H)- thione (Hbzpamt) of composition (ML2) (M= Mn II , Co II , Ni II , Cu II , Zn II and Cd II , HL= Hbzeamt or Hbzpamt), PdLX (L= Hbzeamt or Hbzpamt and X= Cl or Br) and (M(LH)Cl2) (M= Co II , Ni II , or Cu II ). The magnetic moment value of complexes (ML2) of Mn II , Ni II and Cu II occurs in the range of high spin octahedral environment of ligand molecules while Co II complexes show anomalous magnetic moment value. Iron (III) complexes FeL2Cl show magnetic moment value similar to high spin octahedral Fe(III) complexes. The dichloro complexes of Co(II), Ni(II) and Cu(II) are high spin type. The ir spectra of ligands show that molecule exist in thione form in solid state and coordinates as tridentate (N, N, S) donor molecule. The 1 HNMR spectra of ligand in DMSO were recorded to elucidate the structure of ligand" @default.
- W2184495737 created "2016-06-24" @default.
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- W2184495737 date "2013-01-01" @default.
- W2184495737 modified "2023-09-27" @default.
- W2184495737 title "Synthesis, Characterisation and Antimicrobial studies of complexes of metal ions with 4-{(E)-(1-(1H-benzo(d)imidazol-2-yl)ethylidene)amino}-3- methyl-1H-1, 2, 4-triazole-5(4H)-thione and related ligand." @default.
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