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- W2185060712 abstract "The complexes of Co(II), Ni(II) and Cu(II) with N,Ni-bis-(5-X-salicylidene)-4,4i-diaminodibenzyl, abbreviated as H2nXSalPDADB (X = -H, -CH3, -Br) have been synthesized and investigated by elemental analysis, electrical conductance, magnetic, spectral and thermal studies. The molar conductivity data indicate that the complexes are non-electrolytes. Analytical data support 1:1 (M:L) stoichiometry. The reflectance spec- tra along with the magnetic data suggest pseudo-tetrahedral geometry for the complexes. The Schiff bases func- tion as tetradentate ligands coordinating through ON-NO donor system. Substitution in the phenyl ring of the complexes produces shift in the azomethine ν(C=N) stretching vibrational frequency, which is related to the Hammettis substituent perameter (σ). The 1 H-NMR data reveal that all Schiff bases exist in enol-iminic form. Various ESR parameters for copper complexes have been calculated. The compounds have been screened for their biological activities." @default.
- W2185060712 created "2016-06-24" @default.
- W2185060712 creator A5012637179 @default.
- W2185060712 date "2007-07-01" @default.
- W2185060712 modified "2023-09-24" @default.
- W2185060712 title "Synthetic, structural and biological properties of binuclear complexes with some Schiff bases." @default.
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