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- W2185291208 abstract "The Li1+xMxHf2−x(PO4)3 (M=Cr, Fe, Bi) systems have been studied and single phases have been isolated for M=Cr and Fe. The samples have been characterized by X-ray powder diffraction, diffuse reflectance and impedance spectroscopy. There is a reconstructive transition between rombohedral NASICON and orthorhombic Sc2(WO4)3-type structures as a function of x, at very low values, 0.2 and 0.1 for Cr and Fe, respectively. For the Cr series, a further subtle structural change has been observed for x values higher than 1.7. These phases have the Sc2(WO4)3-type framework, but the symmetry is orthorhombic Pcnb at low values of x and monoclinic P21/n at high values. The structural changes are discussed on the basis of the sizes of the cavities left by the two frameworks and the lithium order/disorder in these voids. These materials are ionic conductors and their electrical behaviours are also discussed." @default.
- W2185291208 created "2016-06-24" @default.
- W2185291208 creator A5057640581 @default.
- W2185291208 date "1998-09-02" @default.
- W2185291208 modified "2023-10-02" @default.
- W2185291208 title "NASICON to scandium wolframate transition in Li1+xMxHf2âx(PO4)3 (M=Cr, Fe): structure and ionic conductivity" @default.
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- W2185291208 doi "https://doi.org/10.1016/s0167-2738(98)00207-0" @default.
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